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In a series of 167 children with hematologic malignancy or aplastic anemia receiving dapsone for Pneumocystis (PCP) prophylaxis, 32 (19 percent) developed methemoglobinemia (median level: 9 percent, range 3.5 to 22 percent)

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This seemingly minor change -- the addition of a single methyl group -- can influence copper binding geometry, peptide stability, skin penetration, and biological activity